Abstract

Extinction coefficients have been obtained for solutions of oxalyl chloride diluted with benzene, n-heptane, and me-cyclohexane; and for solutions of diacetyl, acetyl bromide, acetyl chloride, α-methyl acrolein, and crotonaldehyde diluted with benzene and n-heptane. It has been possible to correlate the observed data in the infrared, Raman, and ultraviolet spectra of oxalyl chloride-benzene solutions by postulating a complex formation of the type Ar+[COCl]2−.

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