Abstract

In this work we report the development of a rapid and selective etching strategy to synthesize a dual-yolk/shell nanostructure consisting of semiconductor-metal hybrid nanocrystals and hollow SiO2 for the first time. By utilizing CdSe/CdS/ZnS quantum dot (CSSQD)/SiO2 core/shell nanoparticles as the template and aurate hydroxyl complexes (Au(OH)4 - ) as the Trojan-type inside-out etching agent, rapid formation of CSSQD-Au hybrid nanocrystal dual-yolk and SiO2 hollow shell occur during the reduction of Au(OH)4 - on CSSQD cores

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