Abstract

Heat-resistant two-dimensional (2D) sphere/hemisphere shell array is significant for the fabrication of novel nanostructures. Here large-area, well-ordered arrays of carbonized polystyrene (PS) hollow sphere/hemisphere with controlled size and morphology are prepared by combining the nanosphere self-assembly, kV Ag ion beam modification, and subsequent annealing or chloroform treatment. Potential mechanisms for the formation and evolution of the heat-resistant carbonized PS spherical shell with increasing ion fluence and energy are discussed. Combined with noble metal or semiconductor, these modified PS sphere arrays should open up new possibilities for high-performance nanoscale optical sensors or photoelectric devices.

Highlights

  • Ion beam irradiation is one of the most powerful and well-known methods to modify the surface properties and topography of materials[16,17,18]

  • We present a systematic investigation of the influence of the ion-irradiation parameters on the morphology and structure of PS microsphere array

  • We only show the research results of PS microspheres 820 nm in initial diameter below, even though we have obtained the similar results for 430 nm PS microspheres

Read more

Summary

Shell Arrays by Ion Beam Irradiation and Subsequent Annealing or Chloroform

Xianyin Song[1], Zhigao Dai[1], Xiangheng Xiao[1,5], Wenqing Li1, Xudong Zheng[1], Xunzhong Shang[2], Xiaolei Zhang[1], Guangxu Cai[1], Wei Wu3, Fanli Meng4 & Changzhong Jiang[1]. Large-area, well-ordered arrays of carbonized polystyrene (PS) hollow sphere/hemisphere with controlled size and morphology are prepared by combining the nanosphere self-assembly, kV Ag ion beam modification, and subsequent annealing or chloroform treatment. Materials (e.g. PS, polymethylmethacrylate (PMMA)) are irradiated by a high-energy ion beam, some complex physico-chemical reactions will happen simultaneously, such as the effect of heat deposition, carbonization or cross-linking, surface sputtering effect, etc[19,20,21,22]. These reactions make organic polymer undergo drastic changes in morphology, composition and physicochemical properties. The microstructural characterizations were performed using a JEOL 2010 (HT) transmission electron microscope (TEM) operating at 200 kV

Results and Discussion
Conclusions
Author Contributions
Additional Information

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.