Abstract

AbstractThe Elgin–Franklin complex contains gas condensates in Upper Jurassic reservoirs in the North Sea Central Graben. Upper parts of the reservoirs contain bitumens, which previous studies have suggested were formed by the thermal cracking of oil as the reservoirs experienced temperatures of >150°C during rapid Plio-Pleistocene subsidence. Bitumen-stained cores contaminated by oil-based drilling muds have been analysed by hydropyrolysis. Asphaltene-bound aliphatic hydrocarbon fractions were dominated by n-hexadecane and n-octadecane originating from fatty acid additives in the muds. Uncontaminated asphaltene-bound aromatic hydrocarbon fractions, however, contained a PAH distribution very similar to normal North Sea oils, suggesting that the bitumens may not have been derived from oil cracking.1D basin models of well 29/5b-6 and a pseudo-well east of the Elgin–Franklin complex utilize a thermal history derived from the basin's rifting and subsidence histories, combined with the conservation of energy currently not contained in the thermal histories. Vitrinite reflectance values predicted by the conventional kinetic models do not match the measured data. Using the pressure-dependent PresRo® model, however, a good match was achieved between observed and measured data. The predicted petroleum generation is combined with published diagenetic cement data from the Elgin and Franklin fields to produce a composite model for petroleum generation, diagenetic cement and bitumen formation.

Highlights

  • T hydrocarbon fractions were dominated by n-hexadecane and n-octadecane originating from fatty P acid additives in the muds

  • This study showed that high liquid water pressures could result in the formation of high molecular weight nalkane hydrocarbons, and an increase in the amount of high molecular weight unresolved complex material (UCM) and the asphaltene content in a light API gravity North Sea oil from the Norwegian Oseberg field

  • The free heptane extracts from the two Franklin samples were T compositionally different, probably still impacted by drilling mud contamination. These P extracts contain a low boiling fraction dominated by n-alkanes (n-C11 to n-C20 with a maximum at nE C14), together with a higher boiling fraction composed largely of a unresolved complex mixture ACC (UCM) that elutes over the range of n-C20 to n-C32 (Fig. 6a)

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Summary

Introduction

T hydrocarbon fractions were dominated by n-hexadecane and n-octadecane originating from fatty P acid additives in the muds. Uncontaminated asphaltene-bound aromatic hydrocarbon fractions I contained a PAH distribution very similar to normal North Sea oils, suggesting that the R bitumens may not have been derived from oil cracking. D cement data from Elgin/Franklin to produce a composite model for petroleum generation, E diagenetic cement and bitumen formation. M3 of gas, with both phases currently understood to have formed mainly by the cracking of oil as the temperature of the reservoir increased during the Neogene and Quaternary (Lasocki et al 1999; Vandenbroucke et al 1999). C While the study by Vandenbroucke et al (1999) provides a detailed kinetic evaluation of S both the rate of liquid/gas product generation from a Kimmeridge Clay Formation (KCF) U sourced oil and the composition of the conversion products, it does not include any details N of the composition of the bitumens generated by this reaction. Tar mats and A pyrobitumens often contain little in the way of free hydrocarbons and little M information exists on the source and chemical nature of these ubiquitous solids

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