Abstract
A competitive formation of ‘anti’ symmetric di-CuII and ‘syn’ non-symmetric decarboxylated di-CuII complexes was established from a systematic study of CuII binding to aminocarboxylate-based bis-glycinamide ligands featuring a His/His dyad, due to the Δ–Λ interconversion of backbone conformation which gave rise to anti versus syn binding for the 2nd CuII. The findings provide a facile strategy for the investigation of novel di-CuII mimics.
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