Abstract
Thermolysis of [(C5Me5)2YH]2 in n-octane or benzene yields (C5Me5)2Y(µ-H)Y(η5-C5Me4CH2)(C5Me5), a bis-yttrium-monohydride in which a tetramethylfulvene ligand bridges in a σ–η5 manner between the yttrium atoms; the hydride bridge is asymmetric showing two yttrium–hydrogen coupling constants in the 1H n.m.r. spectrum.
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More From: Journal of the Chemical Society, Chemical Communications
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