Abstract

The formation of a cobalt complex involving the ligand 2,4,6-tripyridyl-s-triazine (TPTZ) is reported. Spectral data, magnetic susceptibility measurements, and conductance values are compatible with a six coordinate, high spin cobalt(II) complex, which in solution is found to be polarographically reducible to a formal univalent state. The reduction potentials of Co(TPTZ) 2 2+ and Co(terpy) 2 2+ are compared and discussed (terpy = 2,2′,2″-terpyridine).

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