Abstract
Abstract To meet the requirements of high strength of tungsten (W) based alloys at high temperature applied in the aerospace field, the preparation and formation of Hf-related ceramic particles in W were studied. It is found that the HfO2 phase with a size of about 500 nm was observed at the grain boundary in both W-0.26 wt.% HfC and W-0.25 wt.% HfH2-0.125 wt.% C systems. Further study of phase stability and thermodynamic properties of Hf(W)-O(C) compounds reveals that the HfO2 phase possesses the most stability of all the Hf-related compounds, and the oxidation of Hf is preferred to the carbonization. It is predicted that more stability of W base metal, higher temperature, and higher carbon concentration can reduce the formation of HfO2 while promoting the formation of the HfC particle phase.
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