Abstract

An isothermal kinetics study of the transformation of Tl-2212 into Tl-2223 has been carried out at four different temperatures. The Tl-2223 and Tl-2212 weight fraction have been deduced from Rietveld analysis of XRD patterns and the transformed fraction α has been calculated for each sample. The results indicate that the transformation is limited by diffusion and particularly by the thickening of large plates after lateral impingement.

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