Abstract
Organometallic ion-radicals are formed during reactions of Cr 2+, V 2+, Eu 2+ and Ti 3+ ions in acid aqueous media with unsaturated carboxylic and α-keto-acids, by direct attack on the carbon of the double bond. Subsequently these ion-radicals may undergo transformation via nucleophilic attack on carbon by a second metal ion, or disproportionation, or olefin elimination, or free radical formation, or dimerization. Examples are given for each type of reaction, and comparisons are made between different metal ions and different ligands.
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