Abstract
connection with another project involving the cleavage of the thiirane ring of cyclohexene episulfide in the presence of trifluoromethylthiocopper, the presence of several unusual cyclic sulfides (5–10, Fig. 1) was observed both in the reaction product and the starting material itself. The formation of these compounds has been rationalized on the presence and participation of the thiyl radical species. Details pertaining to their formation and characterization based on their mass spectral fragmentation behavior are presented in this communication.
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