Abstract

The formation and decay of transient xenon dihydride upon annealing xenon-hydrocarbon systems irradiated with fast electrons at 15 K was monitored by FTIR spectroscopy. It is concluded that XeH 2 is a chemically identical species, which can be generated in different ways. The two bands of these species (positioned at 1181 and 1166 cm −1) show essentially different behaviour with annealing temperature. Evidence for a chemical reaction of xenon dihydride with trans-2-butene occurring in a xenon matrix at 60–70 K was obtained. The addition of electron scavengers results in a dramatic decrease in the XeH 2 yield. It is suggested that xenon dihydride results from H atoms rather than from charged precursors.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.