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Abstract
N-Trifluoroacetyl-L-acosamine 20 and N-trifluoroacetyl-L-daunosamine 21 were formally synthesized from an achiral precursor, methyl sorbate 4, based on enzymatic chiral induction and diastereoselective 1, 4-conjugated addition of benzylamine to the olefinic moiety of the α, β-unsaturated ester 12.
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