Form stable composite phase change materials from palmitic-lauric acid eutectic mixture and carbonized abandoned rice: Preparation, characterization, and thermal conductivity enhancement

Abstract

In this study, novel form stable composite phase change materials (FS-CPCMs) from palmitic-lauric acid (PA-LA) eutectic mixture and carbonized abandoned rice (CAR) were prepared via vacuum impregnation. The CAR served as a good supporting material to prevent PA-LA from leaking and enhanced the thermal conductivity of PA-LA. SEM results showed that the CAR has a highly porous structure consisting of rough micro-pores and PA-LA did not leak from the CAR during the solid-liquid phase transition. DSC indicated that the latent heat and temperature of PA-LA/CAR FS-CPCMs during melt were 135.4J/g and 34.3°C, respectively, whereas, these values were 124.8J/g and 28.6°C during freezing, respectively. The thermal conductivity of PA-LA/CAR FS-CPCMs was 1.83 times that of PA-LA. The heat storage/release rate of the PA-LA/CAR FS-CPCMs is significantly more than that of PA-LA for practical applications. The results obtained from FTIR demonstrated that no new chemical bonds were formed between PA-LA and CAR. TGA and 200-cycle experiments showed that the PA-LA/CAR FS-CPCMs exhibit excellent thermal stability and form-stable performance. The PA-LA/CAR FS-CPCMs thus prepared were safe, environmentally friendly, and cost-effective; hence, they can be used as potential building materials for the applications of thermal energy storage.