Abstract
The half-width γ and cross-relaxation parameter ζ are calculated for a series of rotational transitions on the basis of a rigorous theory taking account of the correlational broadening of the doublet components. The absorption of the doublet lines of the transition J = 4 → 5 for the system NH3-N2 and the transition J = 5→ 6 for NH3-NH3 is analyzed. For the vibrational ground state, analytical expressions are given for the parameters γ and ζ.
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