Abstract
Using the maximum value of the sum of the interaction constants, the CO-factored force field of octahedral M(CO) 5L molecules was solved to give the relations which allow direct calculation of force constants from CO stretching frequencies of the all- 12C 16O molecule. The force constants calculated by these relations were used to predict CO stretching frequencies of isotopically enriched species of some complexes of the type M(CO) 5L. The results obtained showed that there exists a very good agreement between observed and calculated frequencies. This led us to conclude that the solution presented for the force field of M(CO) 5L molecules is a valid solution.
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