Abstract

The microscale structure and size are extremely important factors for gas sensing materials. In this study, hierarchical flower-like ZnO architectures were synthesized by a biomolecular mediated route. The influence of various experiment parameters including reaction time, pH value, and reaction temperature on the formation of ZnO architectures was studied. When used as sensing material, this material possesses a higher sensing response towards ethanol and formaldehyde. Towards 100 ppm of ethanol and formaldehyde, the ZnO sensor can display remarkable sensing responses (Ra/Rg) of 13.6 and 16.5, respectively. These values are higher than or comparable to most of reported ZnO-based gas sensors. In addition, the sensors can show obvious sensing response to 5 ppm of ethanol and formaldehyde, indicating the lower limit of detection. It is proposed that the unique hierarchical microstructure contributes to the enhanced sensing performance.

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