Folded nano-porous graphene-like carbon nitride with significantly improved visible-light photocatalytic activity for dye degradation

Abstract

Abstract Graphitic carbon nitride (g-C 3 N 4 ) prepared by traditional methods has various disadvantages, e.g., small specific surface area, low band gap, high photo-generated carriers recombination and low exfoliation efficiency, which limits its practical application. In this study, folded nano-porous graphene-like g-C 3 N 4 (abbreviated as FNPGLCN) was prepared by a simple but quite effective method of calcining urea in water. The effects of calcination temperature on crystal structure, energy band and microstructure of g-C 3 N 4 were investigated. The photocatalytic activity for methylene blue (MB) degradation under visible-light was evaluated. The results revealed that the FNPGLCN had higher specific surface area (197 m 2 /g) and larger band gap (2.87 eV) than bulk g-C 3 N 4 . With calcination temperature rising from 450 to 500 °C, the pore size and specific surface area of FNPGLCN increased. However, the pore structure almost disappeared and the thickness of g-C 3 N 4 became thinner at 550 °C. Compared with bulk g-C 3 N 4 , the photocatalytic degradation rate of FNPGLCN for MB increased from 0.131 to 1.298 h −1 . The significant enhancement of visible photocatalytic activity was mainly attributed to folded nano-porous structure, which simultaneously improved visible-light absorption range and strength, and enlarged the band gap and specific surface area of g-C 3 N 4 .