Abstract
Two new organically templated zinc phosphites, H 2depda·Zn 3(HPO 3) 4 ( 1) and H 2dmpda·Zn 3(HPO 3) 4 ( 2), have been synthesized under flux conditions, where depda = N, N-diethyl-1,3-propanediamine and dmpda = N, N-dimethyl-1,3-propanediamine. The two compounds have different (3,4)-connected inorganic frameworks constructed by strictly alternating ZnO 4 tetrahedra and HPO 3 pseudo pyramids. The presence of large 12-ring channels in the two open-framework structures is noteworthy.
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