Abstract
Fluorous biphasic catalysis. 2. Synthesis of fluoroponytailed amine ligands along with fluoroponytailed carboxylate synthons, [M(C<sub>8</sub>F<sub>17</sub>(CH<sub>2</sub>)<sub>2</sub>CO<sub>2</sub>)<sub>2</sub>] (M = Mn<sup>2+</sup> or Co<sup>2+</sup>): Demonstration of a perfluoroheptane soluble precatalyst for alkane and alkene functionalization in the presence of <i>tert</i>-butyl hydroperoxide and oxygen gas
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