Abstract
The syntheses of Os(SO 3F) 3 and Rh(SO 3F) 3 by the oxidation of osmium and rhodium metal powder with bis(fluorosulfuryl) peroxide, S 2O 6F 2, are reported. The conditions required for metal oxidation, extremely mild for osmium, and severe for rhodium, and the reaction times represent two extremes in the behaviour of noble metals towards S 2O 6F 2. For Os(SO 3F) 3 evidence from diffuse reflectance and infrared spectra as well as from bulk magnetic susceptibility measurements suggests polymorphism with a slow conversion occurring at room temperature in an excess of S 2O 6F 2.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
