Abstract
Fluoroolefin dipeptide isosteres were synthesized applying the Peterson reaction as a novel method for fluoroolefination. The dipeptide isosteres were elaborated to provide the conformationally constrained analogs ( 1-( R), 1-( S) and 2-( R), 2-( S)) of the Suc-Ala-Gly-Pro-Phe-pNA tetrapeptide, a synthetic substate of cyclophilin.
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