Abstract

The binary selenium fluorides SeF n (n = 2, 4, 6) and Se 2F 2 are considered along with corresponding perfluorohalogenoorgano- selenium compounds with selenium in the oxydation states 1, 2, 4 and 6. For lower selenium fluorides, preparation and characterisation are emphasized. Recent results in the chemistry of SeCF 2, CF 3SeCl, CF 3SeSeCF 3, CF 3Se(O)OM and CF 3Se VI- compounds are presented. A comparison with the corresponding sulfur chemistry is also provided.

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