Abstract
1. A new source of unhydrated fluoride Ion, hexamethylguanidinium fluoride, has been synthesized. 2. Hexamethylguanidinium fluoride adds practically irreversibly to perfluoroisobutylene to form the perfluoro-tert-butyl anion that is stabilized by the hexamethylguanidinium cation. 3. Direct acylation of perfluoro-tert-butyl anion, to give phenyl perfluoro-tert-butyl ketone has been carried out for the first time.
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Schedule a callMore From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
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