Abstract
1. The perfluoroalkyl carbanions generated by the reaction between N,N,N′,N′-tetramethylformamidinium bifluoride and perfluoroolefins are readily acylated with the fluoroanhydrides of carboxylic acids with the formation of perfluoroalkyl alkyl ketones and their enol derivatives. 2. Hydrolysis of the acylates of the enols of perfluoroalkyl alkyl ketones leads to perfluoroalkyl alkyl ketones.
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