Fluorine interaction controlled AIEE phenomenon in an expanded calixbenzophyrin and its vapoluminescent response: turn on emission with volatile ketones and esters

Abstract

Fluorine interaction assisted AIEE characteristic in an expanded calixbenzophyrin is presented by single-crystal X-ray-diffraction analysis and molecular modelling approaches. Selective exposure to volatile organic compounds such as ketones and esters results in the breaking of fluorine interaction, leading to enhanced monomer emission.