Abstract
Chemistry of metal and non-metal fluorides in liquid ammonia is often severely hampered, due to the low solubility of inorganic fluorides. This can be overcome by applying either strongly oxidizing fluorides, appropriate fluoride ion acceptors, or by the reduction or conversion of fluorides using solvated electrons. The article summarizes the state-of-the-art of the chemistry of inorganic fluorides in liquid ammonia, with special emphasis on compounds of beryllium, silver and uranium.
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