Abstract
Potassium tetrafluoroargentate(III) and silver difluoride have similar reactivities as fluorinating agents for benzene in the vapour phase. The products are mainly polyfluorocyclohexanes, together with some decafluorocyclohexene and traces of octafluorocyclohexa-1,4-diene. No polyfluoroaromatic species were found in the products. Fluorination of tetrahydrofuran and cyclohexanone gave breakdown products which showed no evidence of oxygen retention.
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