Abstract
Fluorinated enaminoketones, a new type of ligands, bearing two independent coordination centers (polyether's and fluorinated enaminoketones fragments) have been obtained. The crystal structure of the Cu(II) complex of 1,5- bis-[2-(4′,4′,4′-trifluoro-1′-methyl-3′-oxo-but-1′-enylamino)-phenoxy]-3-oxapentane ( 10) has been elucidated by X-ray crystallography. The results obtained show that the complex 10 consists of two crystallographically independent molecules C 26H 24CuF 6N 2O 5 ( A and B), and the metal atom in the complex 10 has four-coordinated arrangement, as a polyhedron with a distorted square with two nitrogen and two oxygen atoms located in corners.
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