Abstract

Some liquid-repelling coatings stay dry in a deluge of water, while others rebuff oils and organic solvents. Some can withstand rough treatment, shrugging off harsh acids and high temperatures or even healing themselves after being damaged. Now Frank Caruso of the University of Melbourne and colleagues have created a veritable Swiss Army knife of a repellent coating that combines all these properties and more, thanks to its unique chemistry and texture (Nat. Mater. 2018, DOI: 10.1038/s41563-018-0178-2). The coating is a mixture of 1H,1H,2H,2H-perfluorohexyltrichlorosilane (PFTS) and n-butyl cyanoacrylate (n-BCA), combined in a dichloropentafluoropropane solution. When sprayed onto a surface, water vapor in the atmosphere triggers a series of polymerization reactions between PFTS and n-BCA to create a tough, transparent film. The coating contains polymer nanoparticles that aggregate to form a highly textured surface, which may trap tiny pockets of air to help ward off liquids. In tests, the coating repelle...

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