Abstract
Cobalt and manganese complexes provide access to novel fluoroallyl ligands: Fluorinated bis(enyl) ligands can be easily synthesized by metal-induced dimerization of 1,1-difluoroallene and tetrafluoroallene. By using octacarbonyldicobalt the coupling reaction occurs at the central carbon atom of the allene leading to the formation of fluorinated μ-(η3 :η3 -2,3-dimethylenebuta-1,4-diyl) ligands such as those in complex 1. Additional products arise from fluoride abstraction and CO insertion reactions. Decacarbonyldimanganese reacts with 1,1-difluoroallene under C-C coupling of the methylene group to give decacarbonyl-μ-(η1 :η1 -1,1,6,6-tetrafluoro-1,5-hexadiene-2,5-diyl)dimanganese.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
