Abstract
Reaction of ruthenium(III) chloride with the barrelene diolefins (tetrafluoro-benzobarrelene (TFB) or (trimethyltetrafluorobenzobarrelene) (Me 3 TFB) leads to the formation of the polymeric complexes [RuCl 2(barrelene)] n . These compounds react with anionic chelating ligands with formation of new hexacoordinated neutral complexes of the general formulae [Rh(chelate) 2(barrelene)], where chelate = acetylacetonate, tropolonate, salicylal-dehydate and 8-oxyquinolinate. The IR and 1H NMR spectra of the complexes are given and discussed.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
