Abstract
5,7-Diaryl-2-fluoro-4 H-1,3-diazepines have been synthesized from 3-aryl-substituted 2 H-azirines and difluorocarbene. The reaction involves isomerization of azirinium ylide into a 2-aza-1,3-diene which undergoes [4+2]-cycloaddition with the starting azirine followed by ring expansion and dehydrofluorination.
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