Abstract
Treatment of pyrazolyl acetoximes p-RC6H4{CN(H)NCCH}CH2C(Me)NOH (R=OMe, H, F, Cl, CN, NO2) with 1equiv of ZnCl2 leads to the complexes [ZnCl2(p-RC6H4{CN(H)NCCH}CH2C(Me)NOH)] (81–91%). These species exhibit fluorescence at room temperature with emission maxima in the region 460–509nm and biexponential relaxation with τ1=4.63–8.64ns and τ2=0.482–0.955ns, respectively. The zinc complexes were characterized by elemental analyses (C, H, N), HRESI-MS, FTIR, 1H and 13C{1H} NMR, and CP-MAS TOSS 13C{1H} NMR. In addition, two zinc complexes and one pyrazolyl acetoxime were studied by single-crystal X-ray diffraction.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
