Fluorescent hydrogels based on oxidized carboxymethyl cellulose with excellent adsorption and sensing abilities for Ag+

Abstract

Heavy metal contamination in water and soil are harmful and destructive to the environment, it has always been regarded as a big problem. Herein, we developed a self-healing fluorescent hydrogel based on oxidized carboxymethyl cellulose with excellent sensing and adsorption abilities for Ag+. The detection and adsorption effects of hydrogels on heavy metal ions were studied. It turned out that the fluorescent hydrogel has sensitive detection and high adsorption capacity for Ag+, the detection limit was 3.798 μM, and the maximum adsorption capacity was 407 mg/g. The adsorption isotherm fitted the Langmuir model well, and the pseudo-secondary model for adsorption kinetics fitted well. The hydrogel could heal itself without external stimulus, it could be easily regenerated 7 times without loss of adsorption performance. In short, the prepared hydrogel has capability of self-healing, detecting and adsorbing heavy metal ions at the same time, good mechanical strength, these all made it a promising long-life adsorbent and provided a new way for wastewater treatment.