Abstract
A dicopper(II) octamine cage includes selectively the l-glutamate ion in water at pH 7, establishing Cu 2+/–COO − coordinative interactions. In particular, l-glutamate is able to displace the quenched rhodamine indicator from the cage, whose fluorescence is then fully restored. Other typical neurotransmitters (glycine, GABA) and some related amino acids are discriminated.
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