Abstract

Styrene acrylic emulsions (SAEs) have emerged as a promising material for water-based coatings. However, they are still limited by their own defects in practical applications, poor weatherability, and degradation of performance at lower or higher temperatures. Here, we introduce a facile approach to producing fluorescent carbon quantum dots (CQDs) from wood processing residues and fabricating fluorescent CQD/SAE coating films via emulsion-casting. The addition of the fluorescent CQDs enhanced the optical performance of the CQD/SAE coating films. The fluorescent CQDs were prepared via a hydrothermal approach and were obtained after heating at 180 °C for 6 h at a reaction concentration of 50 mg/mL. The synthesized CQDs resulted in a high fluorescence, and the CQDs had an average size of 1.63 nm. Various concentrations of the fluorescent CQDs were doped into the SAE coating film, which improved its optical properties. We also characterized and discussed the products and then explored their optical properties. This study presents the potential of fluorescent CQD/SAE coating films for applications in anti-counterfeiting coatings, fluorescent adhesives, and papermaking.

Highlights

  • Styrene acrylic emulsion (SAE), as a non-crosslinking emulsion with considerable value for industrial applications, is obtained by the emulsion copolymerization of styrene and acrylate monomers

  • We introduce the fabrication of fluorescent carbon quantum dots (CQDs)/SAE coating films via a facile emulsion-casting approach

  • The high-resolution TEM image of the CQDs revealed that the lattice fringes with an interplanar spacing of 0.23 nm were marked by yellow arrows, which indicates that the CQDs possess the crystalline properties of graphitic carbon [17]

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Summary

Introduction

Styrene acrylic emulsion (SAE), as a non-crosslinking emulsion with considerable value for industrial applications, is obtained by the emulsion copolymerization of styrene and acrylate monomers. A styrene acrylic emulsion matrix is used for the preparation of sub-ambient radiative cooling coating materials. It provides a novel avenue for constructing coatings with cooling effects, and substantially expands the potential applications in the construction and energy fields [6]. A polymer with a high electromagnetic interference shielding efficiency has been fabricated from the multiwalled carbon nanotubes incorporated into a styrene acrylic emulsion, showing the obtained product as a potential electromagnetic interference shielding coating material on the building surface [7]. Fabricating the nanomaterial-based styrene acrylic emulsion materials could bring about more exciting properties, as well as promising applications

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