Progress in Organic Coatings | VOL. 148
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Fluorescent brighteners in thiol-acrylate polymerizations: Sunlight-cured coatings and LED-assisted multifuctional intelligent nanoparticles synthesis

Publication Date Nov 1, 2020

Abstract

Abstract Fluorescent brighteners mediated, thiol-ene polymerizations retain the robustness of step-growth mechanism meanwhile introducing new features: biocompatible wavelengths of visible light and aqueous reaction conditions. The proposed visible-light thiol-ene polymerization of trithiol − triene monomer is shown to be an innovative, facile, and highly efficient route that constructs a versatile platform for synthesizing high-performance coatings and multifuctional intelligent nanoparticles, respectively performed in a bulk form and emulsion form. In particular, the achievement of the concept of natural-sunlight-triggered thiol-ene polymerization is extremely valuable for coating synthesis as the method is green and friendly to environment in a sustainable manner. Besides, the resulting poly(thioester) latexes are capable of being applicable as multi-stimuli-responsive nanocarriers sensitive to UV, pH and redox.

Concepts
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Thiol-ene Polymerization
Aqueous Reaction Conditions
Fluorescent Brighteners
Emulsion Form
Bulk Form
Visible Light Conditions
Bulk Emulsion
Sustainable Manner
Visible Conditions
Visible Reaction

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