Abstract
The photodynamics of the two isomers of azobenzene in DMSO after nπ * excitation are monitored via transient absorption and steady state emission spectroscopy. The excited state decay of the cis-form is close to single-exponential with a time constant of 0.1 ps. The trans-isomer decays in a biphasic fashion with characteristic times of 0.34 and 3.0 ps. This biphasic behaviour has no impact on its fluorescence intensity. It is concluded that the fluorescence probes the dynamics in the vicinity of the Franck–Condon region.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.