Abstract
Abstract The fluorescence spectra of coronene and 1,12-benzoperylene have been studied in frozen heptane as a function of pressure (0–30 kbar). The fluorescence red shifts at 77°K are 5 cm−1/kbar and 8.3 cm−1/kbar, respectively. High pressures broaden vibronic bands and increase background intensity. The 0, 0 band becomes more pronounced under pressure. The intensity pattern of the 1,12-benzoperylene fluorescence is altered considerably by compression of the heptane matrix. Permanent changes in the spectra after pressure treatment are very slight compared to the reversible effects of high pressures on the spectral characteristics of these two aromatic hydrocarbons.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
