Abstract

Fluorescence spectra and fluorescence decay kinetics of intramolecular excimers of di(1-pyrenylmethylene)adipate (DPA) and di(1-pyrenylmethylene)ether (DPE) were studied in Langmuir-Blodgett (LB) monolayers consisting of stearic acid (SA) and dipalmitoylphosphatidylcholine (DPPC). Two types of excimers with different lifetimes and different lifetime dependences on temperature were found for both of the compounds. No quenching of excimer fluorescence by oxygen was observed in LB films with SA as the matrix compound. When DPPC was used as a matrix only one type of excimer was quenched by oxygen. Photolysis of DPA and DPE LB films resulted in a dramatic decrease in excimer fluorescence, but negligible changes in the pyrene absorption band.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.