Abstract

Novel B2O3–SiO2–Al2O3–ZnO–Li2O/MgO and B2O3–TeO2–PbO–ZnO–Li2O–Na2O glasses with different concentrations of Tm2O3 were synthesized by using the melt-quench method. All the fabricated samples have been characterized by visible emission spectra and decay times, including near-infrared (NIR) luminescence measurements. For 0.5 mol% Tm3+-doped borotellurite glass, several radiative parameters are evaluated using the Judd-Ofelt parameters. The intensity of all the visible emission bands increased with the increase of Tm2O3 concentration up to 0.5 mol%, and beyond this doping content, luminescence concentration quenching takes place. The luminescence intensity quenching is attributed to energy transfer (ET) processes through cross-relaxation (CR) channels. The visible luminescence decay curves were well fit with a single exponential (for Tm3+: 1D2 level) and double exponential (for Tm3+: 1G4 level) functions for the multicomponent borosilicate samples, while Inokuti-Hirayama model was used for the multicomponent borotellurite glass 1D2 level decay time fit. The derived decay lifetimes of the 1D2 level are found to be much shorter than that of the 1G4 level. In Li2O (alkali) or MgO (alkaline) containing borosilicate samples, pumped under 808 nm laser diode, the 3H4→3F4 (1.458 μm) emission intensity increased from 0.1 to 2.0 mol% Tm3+ ion concentration, indicating negligible CR processes. The computed Full-Width at Half-Maximum (FWHM) values for the 1458 nm emission in 2.0 mol% Tm3+-doped Li and Mg series borosilicate samples are 117 and 125 nm, respectively, while the FWHM value for 0.5 mol% Tm2O3 content doped borotellurite glass is 118 nm. Following the analyzed visible and NIR optical results, the fabricated Tm3+ glasses could be useful for blue laser and S-band optical amplifier applications.

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