Fluorescence Detection of Trace Disinfection Byproducts by Ag Nanoprism-Modulated Lanthanide MOFs

Abstract

Disinfection byproducts (DBPs), as an emerging water pollutant, present increasing concern and risk in public health and water safety. Due to their low concentration levels and inherent similarity in molecular structures, sensitive and accurate determination of DBPs is still a challenge especially for onsite or online detection. Herein, a self-regulated fluorescent probe based on the Ag nanoprism-modified lanthanide metal-organic framework (AgNPR@EuMOF) is designed for trichloroacetic acid (TCAA) detection. The EuMOF is constructed with Eu as the metal node and 5-boronoisophthalic acid as the ligand. By introducing sulfhydryl groups into EuMOF, AgNPR can be anchored on the EuMOF surface through Ag-S bonds, enabling the synthesis of stable AgNPR@EuMOF composites. During the sensing process, the triangle AgNPR will react with the organic halogen molecule, accomplished with the blue shift of surface plasmon resonance absorption peak and the significant change in the fluorescence of EuMOF. This probe can detect TCAA in a wide concentration range (0.1-40 μM) with high sensitivity and specificity. The density functional theory calculation on binding energies between DBPs and AgNPR suggests that TCAA has the largest interaction ability with AgNPR than other DBPs. Moreover, the detection of TCAA in real tap water and swimming pool water is also demonstrated with high accuracy. The reported AgNPR@EuMOF represents one of the pioneer fluorescence probes in DBP detection, which holds great promise for onsite or online analysis of trace DBPs in water.