Fluorene-containing polyhedral oligomericsilsesquioxanes modified hyperbranched polymer for white light-emitting diodes with ultra-high color rendering index of 96

Abstract

In this work, a series of hyperbranched white-emitting conjugated polymers were synthesized with polyfluorene (PF) as the branches and three-dimensional-structured spiro[3.3]heptane-2,6-dispirofluorene (SDF) as the conjugated branching point by one-pot Suzuki polycondensation, where 4,7-dithienyl-2,1,3-benzothiadiazole (DBT) as orange-light emitting unit and fluorene-containing polyhedral oligomericsilsesquioxanes (POSSs) as conjugated linking monomer were introduced into the backbones to obtain white-light emission. The influence mechanism of POSSs for hyperbranched white-emitting polymers was explored by adjusting the feeding ratios of fluorene-containing POSSs (from 1 to 20 ​mol%). The results indicated that the synthesized polymers still maintained the high thermal stabilities, and exhibited the improved amorphous film morphology and hydrophobicity, which were beneficial for obtaining optimized interface between the aqueous hole transport layer Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT: PSS) layer and polymer light-emitting layer in device fabrication. As a consequence, all of the fabricated devices with the hyperbranched polymers as light-emitting layers realized white light-emission, and the optimized device exhibite good electroluminescent (EL) performance with Commission Internationale de l’Eclairage (CIE) coordinates at (0.32, 0.33) and maximum color rendering index (CRI) of 96. The fluorene-containing POSSs modified hyperbranched copolymers with broad full width at half maximum (>284 ​nm) are attractive candidates for sunlight-style white polymer light-emitting diodes.