Abstract

Abstract The treatment of wastewaters with complex load including dyes and heavy metals is a subject of paramount importance since trace amounts of these compounds lead to an enormous pollution problem. The present research proposes an innovative, fast and efficient microemulsion system for simultaneous extraction of a mixture of dyes (Crystal violet and Rhodamine B) and heavy metals (cobalt(II) and copper(II) ions) from such wastewaters. The used microemulsion is an environmental friendly system containing Brij 30 as nonionic surfactant and butyl acetate as organic phase. The effect of various parameters with significant influence on the dye and metals extraction efficiencies has been investigated in order to find out the optimal compositions for an efficient extraction of dyes – heavy metals mixture from aqueous media. The results show that the optimum extraction conditions for this system corresponds to pH = 5, a water to oil volumetric ratio equal to 9 and a concentration of the complexing agent equal to 2 mol/L.

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