Flower-like 3D SnS decorated on nickel metal-organic framework for electrochemical detection of dimetridazole in food samples

Abstract

Dimetridazole (DMZ) is a broad-spectrum antibiotic effective against bacterial and protozoan infections in humans and poultry farms. However, excessive DMZ intake leads to harmful effects. Thus, minimizing its environmental presence is crucial for sustaining daily life. This study presents an innovative approach to construct flower-like SnS particle decorations on a nickel metal-organic framework (Ni-MOF@SnS) as an electrocatalyst for DMZ detection. The Ni-MOF@SnS/GCE sensor exhibits exceptional electrocatalytic behavior, including a significantly reduced detection limit of 1.6 nM, extensive linear ranges from 0.01 μM to 60 μM and from 60 μM to 231 μM at lower and higher DMZ concentrations, respectively. It also shows enhanced sensitivity (0.139 μA μM−1 cm−2) and remarkable selectivity for DMZ detection using differential-pulse voltammetry (DPV). Furthermore, the proposed sensor demonstrates good recovery results with actual food samples.