Abstract

In order to understand the flow instabilities of coupled rotation and thermal-solutal capillary convection of binary mixture in a Czochralski configuration subjected to simultaneous radial thermal and solutal gradients, a series of three-dimensional direct numerical simulation have been conducted. The capillary ratio of the silicon-germanium mixture is −0.2. The rotation Reynolds numbers of crystal and crucible, Res and Rec range from 0 to 3506 and 0 to 1403, respectively. Results show that the basic flow is axisymmetric and steady. It has rich flow structures in the meridian plane, depending on the competitions among the driving forces. With the increase of thermocapillary and rotation Reynolds numbers, the basic flow will transit to three dimensional oscillatory flow. For different combination of rotation rate and thermocapillary Reynolds number, the oscillatory flow can be displayed as spoke patterns which is steady in time but oscillate in space, spoke patterns propagate in azimuthal direction, rotational waves or coexistence of spokes and rotational waves. The crucible rotation has an inhibitory effect on the flow instability, inducing the monotonically increase of critical value for flow transitions, however, for crystal rotation, the critical thermocapillary Reynolds number increases at first and then decreases. When the rotation rate is large, two flow transitions are captured.

Highlights

  • Thermal-solutal capillary convection is ubiquitous in nature and commonly encountered in industrial processes [1,2]

  • The crucible rotation has an inhibitory effect on the flow instability, inducing the monotonically increase of critical value for flow transitions, for crystal rotation, the critical thermocapillary

  • Czochralski (Cz) crystal growth technology is an important method for producing crystals, where a rod-mounted seed crystal dipped into melt and carefully pulled out by controlling the thermal and concentration gradients, crystal rotation and pulling rates [9,10]

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Summary

Introduction

Thermal-solutal capillary convection is ubiquitous in nature and commonly encountered in industrial processes [1,2]. In the material processing industry, the crystal growth process is an important example that the qualities of the crystal materials are closely affected by the flow instabilities resulting from the buoyancy and thermal-solutal convections, since the oscillatory flow induces impurity striations in the crystals [3,4]. Under microgravity conditions, the effect of gravity is minimized [5] and the effect of thermal-solutal capillary flow generated by surface tension gradient is highlighted [6,7,8]. The thermal-solutal capillary forces generated by the surface tension gradient, the centrifugal and Coriolis forces induced by rotation are coupled and make the flow become very complex. Further understanding of such coupled flow and ensuing instabilities is expected to improve the quality of crystal growth

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