Flexural strength optimisation of a leucite reinforced glass ceramic

Abstract

Objectives: The aims of the study were to process a ceramic material with a fine leucite particle size using hot pressing techniques, to increase the flexural strength, reliability and ease of use. Methods: A starting glass composition of wt%; 64.2% SiO 2, 16.1% Al 2O 3, 10.9% K 2O, 4.3% Na 2O, 1.7% CaO, 0.5% LiO and 0.4% TiO 2 was used to produce a leucite reinforced ceramic material. Twenty-one porcelain discs were produced by sintering the ceramic frit (group 1) and sixty-three discs by heat pressing the frit (groups 2, 3 and 4). Twenty-one Empress 1 ceramic discs were also heat pressed (group 5). Disc specimens were tested using the biaxial flexure test at a crosshead speed of 0.15 mm/min and the data analysed using the Scheffé F multiple comparison test and Weibull statistics. Specimens were characterised using X-ray diffraction (XRD), secondary electron imaging and energy dispersive X-ray analysis where applicable. Results: The heat pressed groups (2, 3 and 4) had higher mean biaxial flexural strengths and characteristic strength values than groups 1 and 5 ( p<0.05). XRD revealed the presence of tetragonal leucite in all test groups. Fine leucite crystals, tabular platelets and minimal matrix microcracking were found in the microstructure of test groups (1–4) with a more uniform leucite distribution in the heat pressed specimen groups (2, 3 and 4), which were associated with a significant increase in the biaxial flexural strength and reliability. Significance: Optimisation of the microstructure by producing a fine microstructure and controlling the distribution via the correct pressing parameters may be extremely advantageous in these systems.