Abstract

Flexible and transparent applications have become an emerging technology and have shifted to the forefront of materials science research in recent years. Transparent conductive oxide films have been applied for flat panel displays, solar cells, and transparent glass coatings. However, none of them can fulfill the requirements for advanced transparent flexible devices, such as high-frequency applications. Here, we present a promising technique for transparent flexible conducting oxide heteroepitaxial films: the direct fabrication of epitaxial molybdenum-doped indium oxide (IMO) thin films on a transparent flexible muscovite substrate. An n-type epitaxial IMO film is demonstrated with a mobility of 109 cm2 V−1 s−1, a figure of merit of 0.0976 Ω−1, a resistivity of 4.5 × 10−5 Ω cm and an average optical transmittance of 81.8% in the visible regime. This heteroepitaxial system not only exhibits excellent electrical and optical performance but also shows excellent mechanical durability. Our results illustrate that this is an outstanding way to fabricate transparent and flexible conducting elements for the evolution and expansion of next-generation smart devices.

Highlights

  • Transparent conductive oxides (TCOs) exhibit impressive properties, including excellent electrical conductivity and high optical transmittance in the visible light range[1,2]

  • Cubic bixbyite indium tin oxide (ITO) {400} and hexagonal Al-doped ZnO (AZO) {101} exhibited six peaks at 60° intervals, which indicates the existence of multidomain indium oxide (IMO) and single crystalline AZO films on the muscovite substrate

  • To study the microstructure of the IMO/AZO/mica heterostructure as well as explore the heteroepitaxy, interfaces between the thin films and substrate were investigated by transmission electron microscopy (TEM)

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Summary

Introduction

Transparent conductive oxides (TCOs) exhibit impressive properties, including excellent electrical conductivity and high optical transmittance in the visible light range[1,2] They have attracted great interest due to their potentially disruptive application in optoelectronics, including flat panel displays, light-emitting diodes, thinfilm transistors, solar cells and a variety of other applications that use both their electronic and transmittance features[3,4,5,6]. With their dramatically advanced properties for the integration of additional functionalities, flexible electronics- and numerous-related applications have become important research directions for soft technologies and wearable electronics[7,8].

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