Flexible phase change materials for low temperature thermal management in lithium-ion batteries

Abstract

The performance of Li-ion batteries can degrade dramatically at cold ambient temperatures. The excess heat generated during battery operation can be stored by PCMs and then released at low ambient temperatures to insulate the battery. However, PCMs inevitably suffer from easy leakage and poor adaptability. In this study, we prepared a novel Oct/SEBS composite PCM and applied it in a low-temperature Li-ion battery thermal management system. The prepared Oct/SEBS has good shape stability, a sufficiently high latent heat (187.7 J/g), and thermally induced flexibility properties. In addition, the BTMS containing CPCM can exhibit excellent thermal insulation performance, which can insulate the Li-ion battery for more than 30 min even at −20 °C and increase the discharge capacity from 3.78 Ah to 5.49 Ah, which is very beneficial for the operation of the Li-ion battery at low temperatures.